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Copper(I) and silver(I) complexes of 1,5-methylene- and diethylmethylene-bridged bis(oxazoline) ligands. In situ Cu(II)-catalyzed oxidation of methylene bridge |
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| Authors: | Vesna ?aplar Zlata Raza Vladislav Tomiši? Josip Po?ar Mladen ?ini? |
| Institution: | a Laboratory for Supramolecular and Nucleoside Chemistry, Ru?er Boškovi? Institute, PO Box 180, 10002 Zagreb, Croatia b Laboratory for Stereoselective Catalysis and Biocatalysis, Ru?er Boškovi? Institute, PO Box 180, 10002 Zagreb, Croatia c Laboratory of Physical Chemistry, Faculty of Science, University of Zagreb, PO Box 163, 10001 Zagreb, Croatia |
| Abstract: | Silver(I) and copper(I) complexes of C2-symmetric bis(oxazoline) ligands were studied by UV, NMR, IR, EPR and ES-MS spectroscopies. The stability constants of the Ag-1a and Ag-1b complexes with 1:1 and 1:2 stoichiometries in acetonitrile were determined by NMR spectrometric titrations. The evidence of tetrahedral coordination for complex (Ag(1a)2(+ was obtained from the complexation induced shifts (CIS) and NOEs. Mass spectra revealed the Cu(II) mediated oxidation of methylene bridge in copper complexes of 1a and 1b, which was in accordance with the UV, NMR, IR and EPR findings. The efficiency of Cu(I) complexes of methylene-bridged 1,5-bis(oxazoline)s 1 as chiral catalysts in stereoselective cyclopropanation of styrene with ethyl diazoacetate, was compared to that of the dialkylmethylene-bridged 1,5-bis(oxazoline)s 2. |
| Keywords: | Bis(oxazoline) Metal complex Chiral catalysts |
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