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Aluminum dodecatungstophosphate (AlPW12O40) as a non-hygroscopic Lewis acid catalyst for the efficient Friedel-Crafts acylation of aromatic compounds under solvent-less conditions
Authors:Habib Firouzabadi  Nasser Iranpoor  Farhad Nowrouzi
Institution:Department of Chemistry, Shiraz University, Shiraz 71454, Iran
Abstract:Stable and non-hygroscopic aluminum dodecatungstophosphate (AlPW12O40), which is prepared easily from cheap and commercially available compounds was found to be an effective catalyst for Friedel-Crafts acylation reactions using carboxylic acids, acetic anhydride and benzoyl chloride in the absence of solvent under mild reaction conditions.
Keywords:Freidel-Crafts acylation  Poly oxometalate  Aluminum dodecatungstophosphate  Solvent-free
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