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A modular route to nonracemic cyclo-NOBINs. Preparation of the parent ligand for homo- and heterogeneous catalysis
Authors:Bruce H Lipshutz  D.J Buzard  Christina Olsson  Kevin Noson
Affiliation:Department of Chemistry and Biochemistry, University of California, Santa Barbara, CA 93106-9510, USA
Abstract:A sequence which combines a nonracemic tether, a naphthyl diol, and an aminonaphthol has been developed leading to the new ligand cyclo-NOBIN, which can easily be mounted onto polystyrene. Opportunities for extending the route to substituted cyclo-NOBINs are also discussed.
Keywords:Binaphthyls   NOBINs   Ligands   Asymmetric catalysis   Heterogeneous catalysis
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