A modular route to nonracemic cyclo-NOBINs. Preparation of the parent ligand for homo- and heterogeneous catalysis |
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Authors: | Bruce H Lipshutz D.J Buzard Christina Olsson Kevin Noson |
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Affiliation: | Department of Chemistry and Biochemistry, University of California, Santa Barbara, CA 93106-9510, USA |
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Abstract: | A sequence which combines a nonracemic tether, a naphthyl diol, and an aminonaphthol has been developed leading to the new ligand cyclo-NOBIN, which can easily be mounted onto polystyrene. Opportunities for extending the route to substituted cyclo-NOBINs are also discussed. |
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Keywords: | Binaphthyls NOBINs Ligands Asymmetric catalysis Heterogeneous catalysis |
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