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| 含烯烃配体的过渡金属卡宾配合物的研究V:新型异构化的环己二烯(二羰基)[乙氧基(芳基)卡宾]铁配合物的合成和结构 | |
| 引用本文： | 陈家碧,雷桂馨,张泽莹,唐有祺. 含烯烃配体的过渡金属卡宾配合物的研究V:新型异构化的环己二烯(二羰基)[乙氧基(芳基)卡宾]铁配合物的合成和结构[J]. 化学学报, 1987, 45(4): 418-420 |
| 作者姓名： | 陈家碧 雷桂馨 张泽莹 唐有祺 |
| 作者单位： | 中国科学院上海有机化学研究所;北京大学物理化学研究所 |
| 摘 要： | 报导了用含环状共轭双烯配体的1,3-环己二烯三羰基铁(1)与芳基锂在低温下的反应,并用Et3OBF4烷基化,以观察环烯烃配体的反应活性及其对卡宾配合物异构化的影响.并研究不同烯烃配体和芳烃取代基对产物的影响. |
| 关 键 词： | 晶体结构测定 铁络合物 羰基络合物 碳烯 结构分析 过渡金属络合物 环己二烯P |
Studies on olefin-coordinating transition metal carbene complexes V: Synthesis and structure of new type of isomerized products of cyclohexadiene (dicarbonyl)(ethoxy(aryl)carbene)iron complexes |
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| CHEN JIABI,LEI GUIXIN,ZHANG ZEYING,TANG YOUQI. Studies on olefin-coordinating transition metal carbene complexes V: Synthesis and structure of new type of isomerized products of cyclohexadiene (dicarbonyl)(ethoxy(aryl)carbene)iron complexes[J]. Acta Chimica Sinica, 1987, 45(4): 418-420 | |
| Authors: | CHEN JIABI LEI GUIXIN ZHANG ZEYING TANG YOUQI |
| Abstract: | Title compounds I (R = H, 3-Me, 4-Me, 4-MeO, 4-CF3) were prepared by treating 1,3-cyclohexadiene(tricarbonyl)iron with RC6H4L in Et2O at -50 to -60?followed by alkylation of the acylcarbonyl lithium salts with Et3OBF4 in aqueous solution at 0? The crystal structure of I (R = H) was determine |
| Keywords: | CRYSTAL STRUCTURE DETERMINATION IRON COMPLEX CARBONYL COMPLEX CARBENE STRUCTURAL ANALYSIS TRANSITION METAL COMPLEX CYCLOHEXADIENE P |
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