| 红外光谱定量法研究醇在正烷烃中的氢键缔合 |
| |
| 引用本文： | 许建和,孙贤达,卢为琴,高鸿锦.红外光谱定量法研究醇在正烷烃中的氢键缔合[J].物理化学学报,1992,8(3):358-363. |
| |
| 作者姓名： | 许建和 孙贤达 卢为琴 高鸿锦 |
| |
| 作者单位： | Department of Chemistry, Tsinghua University, Beijing 100084 |
| |
| 摘 要： | 测定了正十六醇-正己烷烃溶液(0.01～0.20 mol·L~(-1))在不同浓度下的红外光谱, 并用付里叶自去卷积-曲线拟合法(Fourier Self-decon-volution and curve-fitting)对谱图进行了解析。结果将醇羟基峰归属为: (1)单体羟基峰(3646.6 m~(-1))、(2)链状缔合体末端游离羟基峰(3633.8 cm~(-1))、(3)环状二聚体羟基峰(3535.1 cm~(-1))、(4)链式二聚体缔合羟基峰(3474c m~(-1))和(5)链状多聚体组合羟基峰(3337 cm~(-1))五种类型, 并得出它们随浓度的分布规律。
|
| 关 键 词： | 红外光谱定量法 醇-烷体系 氢键缔合 |
| 收稿时间： | 1991-02-09 |
| 修稿时间： | 1991-07-30 |
STUDY OF HYDROGEN BOND ASSOCIATION OF ALCOHOL MOLECULES IN ALKANES BY IR QUANTITATIVE ANALYSIS |
| |
| Xu Jianhe,Sun Xianda,Lu Weiqin,Gao Hongjin.STUDY OF HYDROGEN BOND ASSOCIATION OF ALCOHOL MOLECULES IN ALKANES BY IR QUANTITATIVE ANALYSIS[J].Acta Physico-Chimica Sinica,1992,8(3):358-363. |
| |
| Authors: | Xu Jianhe Sun Xianda Lu Weiqin Gao Hongjin |
| |
| Institution: | Department of Chemistry, Tsinghua University, Beijing 100084 |
| |
| Abstract: | The IR spectra of n-C_(16)H_(33)OH/n-C_6H_(14)(n-hexadecanol/n-hexane) system in seven different alcohol concentrations (0.01-0.20 mol·L~(-1)) were measured and analysed by combined Fourier self-deconyolution and curve-fitting methods. The types of associa-tion in the system can be identified and their distribution can be evaluated. |
| |
| Keywords: | IR quantitative analysis Alcohol/Alkane system Hydrogen bond association |
| 本文献已被 CNKI 维普 等数据库收录！ |
| 点击此处可从《物理化学学报》浏览原始摘要信息 |
| 点击此处可从《物理化学学报》下载免费的PDF全文 |
