Double quantum transitions in paramagnetic resonance

The theory of double quantum transitions of the M=±2 type, with regard to inhomogeneously broadened spin systems is studied in this paper with the approximation²T₂T₃ 1. We suppose that the inhomogeneous broadening is formed by an inhomogeneous crystal field. The obtained results describe the magnitude of absorption as a function of the h.f. power and also describe the shape of the absorption curve. It is demonstrated that in inhomogeneously broadened spin systems the absorption curve of double quantum transitions has the form of the difference of two different Lorentz's curves and that at the saturation (²T₂T₁ 1) the absorption increases with the cube of the h.f. field intensity. The shape of the curves is expressed by means of phenomenological relaxation constants of the system.

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M=±2 ²T₂T₃ 1. , - . . , (²T₂T₁ 1) . .