| A new approach to the synthesis of α-chlorocycloalkanones |
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| 引用本文： | Xing Hai Li Xin Ling Yang Xiao Mei Liang Zhen Peng Kai Yun Ling Fu Heng Chen Dao Quan Wang. A new approach to the synthesis of α-chlorocycloalkanones[J]. 中国化学快报, 2007, 18(12): 1476-1478. DOI: 10.1016/j.cclet.2007.10.022 |
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| 作者姓名： | Xing Hai Li Xin Ling Yang Xiao Mei Liang Zhen Peng Kai Yun Ling Fu Heng Chen Dao Quan Wang |
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| 作者单位： | Xing Hai Li Xin Ling Yang Xiao Mei Liang Zhen Peng Kai Yun Ling Fu Heng Chen Dao Quan Wang Department of Applied Chemistry，China Agricultural University，Beijing 100094，China |
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| 基金项目： | We acknowledge financial support of this investigation by the National Basic Research Program of China (No.2003CB 114407). |
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| 摘 要： | α-Chlorocycloalkanones(Ⅳ) were synthesized from cycloalkanones via potassiumα-oxocycloalkylsulfonates(Ⅱ).A two-step mechanism was proposed to explain the formation ofⅣfromⅡ.
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| 关 键 词： | α-Chlorocycloalkanones Synthesis Potassiumα-oxocycloalkylsulfonates |
| 收稿时间： | 29 June 2007. |
A new approach to the synthesis of α-chlorocycloalkanones |
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| Xing Hai Li, Xin Ling Yang, Xiao Mei Liang, Zhen Peng Kai, Yun Ling, Fu Heng Chen,Dao Quan Wang,. A new approach to the synthesis of α-chlorocycloalkanones[J]. Chinese Chemical Letters, 2007, 18(12): 1476-1478. DOI: 10.1016/j.cclet.2007.10.022 |
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| Authors: | Xing Hai Li Xin Ling Yang Xiao Mei Liang Zhen Peng Kai Yun Ling Fu Heng Chen Dao Quan Wang |
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| Affiliation: | aDepartment of Applied Chemistry, China Agricultural University, Beijing 100094, China |
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| Abstract: | α-Chlorocycloalkanones (IV) were synthesized from cycloalkanones via potassium α-oxocycloalkylsulfonates (II). A two-step mechanism was proposed to explain the formation of IV from II. |
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| Keywords: | α -Chlorocycloalkanones Synthesis Potassium α -oxocycloalkylsulfonates |
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