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Origin of Polycyclic Aromatic Hydrocarbons (PAH) in Recent Sediments from the Continental Shelf of the “Golfe de Gascogne” (Atlantic Ocean) and in the Gironde Estuary
Authors:Teresa A P Rocha  Joãto ABP Oliveira  Armando C Duarte
Institution:Department of Chemistry , University of Aveiro , 3810-193, Aveiro, Portugal
Abstract:Abstract

Several aromatic series have been analysed on sediment extracts by high performance liquid chromatography coupled (HPLC) and by high resolution Shpol'skii spectroscopy. HPLC coupled to a programmable spectrofluorometer as detector has been used for the detection of the sixteen PAH priority pollutants recommended by the US Environmental Protection Agency. Relative distribution in methylated phenanthrene, chrysene, and pyrene series have been examined by high resolution spectrofluorometry in Shpol'skii matrices for the determination of the sources of aromatic matter in the sediments. These complementary studies would provide useful information on the origin of PAH in marine sediments.
Keywords:Polycyclic aromatic hydrocarbons (PAH)  high performance liquid chromatography  Shpol'skii effect  estuarine and marine sediments  sixteen PAH priority pollutants  methylphenanthrenes  methylchrysenes  methylpyrenes  quantitative analysis  
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