| 基于烷基锌催化的不对称Henry反应研究进展 |
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| 引用本文： | 李高伟,赵文献,郭蕊,刘新明,郭保国,王敏灿.基于烷基锌催化的不对称Henry反应研究进展[J].化学研究,2010,21(5):107-112. |
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| 作者姓名： | 李高伟 赵文献 郭蕊 刘新明 郭保国 王敏灿 |
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| 作者单位： | 1. 商丘师范学院,化学系,商丘师范学院有机新材料合成重点实验室,河南,商丘,476000
2. 郑州大学,化学系,河南省化学生物与有机化学重点实验室,河南,郑州,450052 |
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| 摘 要： | Henry反应是一类有效的碳碳键形成反应,其产物邻硝基醇可进一步转化为含氮、氧原子的有机中间体.根据催化剂的结构类型对基于烷基锌金属络合催化的不对称Henry反应进行了综述.
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| 关 键 词： | Henry反应 β-硝基醇 烷基锌 研究进展 |
Research Progress in Catalytic Asymmetric Henry Reaction Based on Alkylzinc Reagents |
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| LI Gao-wei,ZHAO Wen-xian,GUO Rui,LIU Xin-ming,GUO Bao-guo,WANG Min-can.Research Progress in Catalytic Asymmetric Henry Reaction Based on Alkylzinc Reagents[J].Chemical Research,2010,21(5):107-112. |
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| Authors: | LI Gao-wei ZHAO Wen-xian GUO Rui LIU Xin-ming GUO Bao-guo WANG Min-can |
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| Institution: | 1.Department of Chemistry and Key Laboratory of New Organic Materials Synthesis,Shangqiu Normal University,Shangqiu 476000,Henan,China;2.Department of Chemistry and Henan Key Laboratory of Chemical Biology and Organic Chemistry,Zhengzhou University,Zhengzhou 450052,Henan,China) |
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| Abstract: | A review is provided of research progress in asymmetric Henry reaction based on alkylzinc reagents in relation to structure types of chiral catalysts.It is pointed out that Henry reaction is one of the powerful carbon-carbon bond formation reactions;the resulting product of the reaction,β-nitroalcohol,can be transformed into a number of nitrogen-and oxygen-containing derivatives. |
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| Keywords: | Henry reaction β-nitroalcohol alkyl zinc research progress |
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