Structure and Extractive Ability of 1-Alkyl- and 3-Methyl-1-phenyl-2-pyrazolin-5-ones |
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Authors: | A. E. Lesnov E. A. Sazonova P. T. Pavlov |
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Affiliation: | (1) Institute of Technical Chemistry, Ural Branch, Russian Academy of Sciences, Perm, Russia;(2) Perm State University, Perm, Russia |
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Abstract: | Extractive ability of 1-substituted 3-methylpyrazol-5-ones (LH) is studied. From acidic chloride complexes, ionic thallium(III) associates (LH2)[TlCl4] are extracted; from trichloroacetate, coordination scandium complexes Sc(LH)4(CCl3COO)3; and from ammine, copper(II) complexes CuL2. The extractive ability decreases in the order R = C7H15 > C6H13 > C5H11 > C6H5 > C4H9.__________Translated from Zhurnal Obshchei Khimii, Vol. 75, No. 2, 2005, pp. 326–330.Original Russian Text Copyright © 2005 by Lesnov, Sazonova, Pavlov. |
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