| Synthesis and Crystal Structure of Dissymmetrical Double Schiff Base Cu（Ⅱ） Homobinuclear and Cu（Ⅱ）-Mg（Ⅱ）-Cu（Ⅱ） Heterotrinuclear Complexes |
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| 引用本文： | 陶偌偈 梅崇珍 刘秉涛 牛景杨. Synthesis and Crystal Structure of Dissymmetrical Double Schiff Base Cu（Ⅱ） Homobinuclear and Cu（Ⅱ）-Mg（Ⅱ）-Cu（Ⅱ） Heterotrinuclear Complexes[J]. 中国化学, 2006, 24(11): 1559-1563. DOI: 10.1002/cjoc.200690292 |
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| 作者姓名： | 陶偌偈 梅崇珍 刘秉涛 牛景杨 |
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| 作者单位： | [1]Institute of Molecular ＆ Crystal Engineering, Chemistry and Chemical Engineering College of Henan University, Kaifeng 475001, China [2]Department of Environmental Sciences and Engineering, North China Institute of Water Conservancy and Hydroelectric Power, Zhengzhou 450008, China |
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| 基金项目： | Project supported by the Natural Science Foundation of Henan Province （No. 0311020800）. |
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| 摘 要： | Homobinuclear complex （HCuL）2 （1） （H3L： N-3-carboxylsalicylidene-N＇-salicylaldehyde-1,2-diaminoethane） was obtained from self-organization of the reported complex HCuL, and its crystal structure was determined through X-ray diffraction at room temperature. The crystal of complex 1 belongs to monolinic system, the space group Cc, a=2.5326（5） nm, b=0.88861（18） nm, c=1.3738（3） nm, β=96.95（3）°, Z=4, R1=0.0520, wR2=0.1185. （HCuL）2 is a dimeric molecule and has extended phenolic oxygen-bridged structure. In addition, using mononuclear complex HCuL as building blocks, Cu（Ⅱ）-Mg（Ⅱ）-Cu（Ⅱ） heterotrinuclear complex 2 was synthesized, and its crystal structure also has been determined by X-ray analysis. The crystal of complex 2 is of monoclinic system, space group Pc, a=1.1816（2） nm, b=1.5599（3） nm, c=1.9642 （4） nm, β=98.22°, Z=2, R1=0.0701, wR2=0.1498. Each dissymmetricai cell unit of complex 2 contains two heterotrinucler neutral molecules： {[CuL（H2O）]Mg[CuL（CH3OH）]} and {[CuL]Mg[CuL（H2O）]}.
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| 关 键 词： | 不对称双席夫碱 同质双核体 异构三核体 晶体结构 铜（Ⅱ）配合物 |
| 收稿时间： | 2006-02-22 |
| 修稿时间： | 2006-02-222006-06-12 |
Synthesis and Crystal Structure of Dissymmetrical Double Schiff Base Cu(II) Homobinuclear and Cu(II)‐Mg(II)‐Cu(II) Heterotrinuclear Complexes |
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| TAO, Ruo-Jie, MEI, Chong-Zhen, LIU, Bing-Tao, NIU, Jing-Yang. Synthesis and Crystal Structure of Dissymmetrical Double Schiff Base Cu(II) Homobinuclear and Cu(II)‐Mg(II)‐Cu(II) Heterotrinuclear Complexes[J]. Chinese Journal of Chemistry, 2006, 24(11): 1559-1563. DOI: 10.1002/cjoc.200690292 |
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| Authors: | TAO Ruo-Jie MEI Chong-Zhen LIU Bing-Tao NIU Jing-Yang |
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| Abstract: | Homobinuclear complex (HCuL)2 ( 1 ) (H3L: N‐3‐carboxylsalicylidene‐N′‐salicylaldehyde‐1,2‐diaminoethane) was obtained from self‐organization of the reported complex HCuL, and its crystal structure was determined through X‐ray diffraction at room temperature. The crystal of complex 1 belongs to monolinic system, the space group Cc, a=2.5326(5) nm, b=0.88861(18) nm, c=1.3738(3) nm, β=96.95(3)°, Z=4, R1=0.0520, wR2=0.1185. (HCuL)2 is a dimeric molecule and has extended phenolic oxygen‐bridged structure. In addition, using mononuclear complex HCuL as building blocks, Cu(II)‐Mg(II)‐Cu(II) heterotrinuclear complex 2 was synthesized, and its crystal structure also has been determined by X‐ray analysis. The crystal of complex 2 is of monoclinic system, space group Pc, a=1.1816(2) nm, b=1.5599(3) nm, c=1.9642 (4) nm, β=98.22°, Z=2, R1=0.0701, wR2=0.1498. Each dissymmetrical cell unit of complex 2 contains two heterotrinucler neutral molecules: {[CuL(H2O)]Mg[CuL(CH3OH)]} and {[CuL]Mg[CuL(H2O)]}. |
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| Keywords: | dissymmetrical double Schiff base homobinuclear heterotrinuclear crystal structure |
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