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高交联大孔苯乙烯/二乙烯苯共聚物的合成及其孔结构的研究Ⅱ
引用本文:于占如,史作清,郭贤权,何炳林.高交联大孔苯乙烯/二乙烯苯共聚物的合成及其孔结构的研究Ⅱ[J].高分子学报,1988,0(3):207-212.
作者姓名:于占如  史作清  郭贤权  何炳林
作者单位:南开大学高分子化学研究所 天津 (于占如,史作清,郭贤权),南开大学高分子化学研究所 天津(何炳林)
摘    要:本文对高交联大孔苯乙烯/二乙烯苯共聚物在干态、湿态与溶胀态的孔结构进行了研究。结果表明,在不同的状态中,高交联共聚物的孔结构是不相同的,它们的孔结构会发生变化。但是,它们的孔结构变化远小于低交联共聚物,也就是说,高交联大孔共聚物的孔结构比低交联共聚物的孔结构稳定。 鉴于高交联大孔共聚物的孔结构较稳定,作者把它用作高效液相色谱的进行了初步实验。结果表明,高交联共聚物可做为高效液相色谱的载体固定相。

关 键 词:苯乙烯/二乙烯苯共聚物  高交联  孔结构稳定性  高效液相色谱
收稿时间:1985-11-21

STUDIES ON THE SYNTHESIS AND THE POROUS STRUCTURE OF THE HIGH CROSSLINKING STYRENE-DIVINYL BENZENE COPOLYMERS Ⅱ
YU Zhan-ru,SHI Zuo-qing,GUO Xian-quan,HE Bing-lin.STUDIES ON THE SYNTHESIS AND THE POROUS STRUCTURE OF THE HIGH CROSSLINKING STYRENE-DIVINYL BENZENE COPOLYMERS Ⅱ[J].Acta Polymerica Sinica,1988,0(3):207-212.
Authors:YU Zhan-ru  SHI Zuo-qing  GUO Xian-quan  HE Bing-lin
Institution:Institute of Polymer Chemistry; Nankai University; Tianjin
Abstract:The authors studied the pore stability of the high crosslinking copolymers in different state. It is shown that the porous structure of the copolymers changes as a result of the treatment with different solvents. However, the porous structure of the high crosslinking copolymers is more stable than that of the low crosslinking copolymers.As a result of the high stability of the copolymers, which could resist the high impact applied, the authors tried to test it as a carrier for the high performance liquid chromatography. From preliminary experiments, it is shown that the high crosslinking copolymers might be used as a carrier for the high performance liquid chromatography.
Keywords:Porous structure  High crosslinking styrene-divinyl benzene copolymer  Pore stability  High performance liquid chromatography  
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