Room Temperature CP Bond Formation Enabled by Merging Nickel Catalysis and Visible‐Light‐Induced Photoredox Catalysis |
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| Authors: | Jun Xuan Ting‐Ting Zeng Prof Dr Jia‐Rong Chen Dr Liang‐Qiu Lu Prof Dr Wen‐Jing Xiao |
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| Institution: | 1. CCNU‐u Ottawa Joint Research Centre, Key Laboratory of Pesticide & Chemical Biology, Ministry of Education, College of Chemistry, Central China Normal University (CCNU), 152 Luoyu Road, Wuhan, Hubei 430079 (China) http://chem‐xiao.ccnu.edu.cn/;2. Collaborative Innovation Center of Chemical Science and Engineering, Tianjin (China), State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, 345 Lingling Road, Shanghai 200032 (China) |
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| Abstract: | A novel and efficient C?P bond formation reaction of diarylphosphine oxides with aryl iodides was achieved by combining nickel catalysis and visible‐light‐induced photoredox catalysis. This dual‐catalytic reaction showed a broad substrate scope, excellent functional group tolerance, and afforded the corresponding products in good to excellent yields. Compared with the previously reported use of photoredox/nickel dual catalysis in the construction of C?C bonds, the methodology described herein was observed to be the first to allow for C‐heteroatom bond formation. |
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| Keywords: | C P bond formation dual catalysis nickel photochemistry radicals |
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