Comparison of modifiers for determination of arsenic, antimony and selenium by atomic absorption spectrometry with atomization in graphite tube or hydride generation and in-situ preconcentration in graphite tube |
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Authors: | Przemyslaw NiedzielskiMarcin Siepak Jerzy Siepak |
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Institution: | a Department of Water and Soil Analysis, Adam Mickiewicz University, Drzymaly Street 24, 60-613 Poznan, Poland b Department of Hydrogeology and Waters Protection, Adam Mickiewicz University, Maków Polnych Street 16, 61-686 Poznan, Poland |
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Abstract: | The study was performed to compare the effect of magnesium modifier (magnesium nitrate) with that of other modifiers (palladium nitrate and nickel nitrate) in determination of arsenic, antimony and selenium by atomic absorption spectroscopy with atomization in a graphite tube, with generation of hydrides and in situ preconcentration in a graphite tube. The assumed criterion of a modifier performance was the magnitude of the analytical signal. It was found that in determinations with atomization in a graphite furnace the effects of all these modifiers were comparable, while in those with hydride generation and in situ preconcentration in a graphite tube the magnesium modifier showed poorer performance (25% decrease of the analytical signal). In determinations of arsenic and selenium the analytical signal obtained with magnesium salt as a modifier was comparable with those obtained in the presence of all other modifiers. |
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Keywords: | Arsenic Antimony Selenium Modifiers Graphite furnace atomic absorption spectrometry In-situ hydride trapping |
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