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Studies toward the synthesis of dienophile unit of methyl sarto-tuoate |
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| Authors: | CHEN Xin-Chao FAN Chun-Feng XU Xing-Xiang |
| Institution: | CHEN,Xin-Chao FAN,Chun-Feng XU,Xing-XiangShanghai Institute of Organic Chemistry,Chinese Academy of Sciences,354 Fenglin La,Shanghai 200032,China |
| Abstract: | The preparation of C3-C14 fragment of the dienophile unit of methyl sartotuoate is described.The key steps included Roush reaction and CuI catalyzed epoxy-opening reaction of i-PrMg-Br. |
| Keywords: | Methyl sartotuoate Roush reaction Sharpless AE reaction synthesis |
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