Metal hydroxides as catalysts for the Baeyer-Villiger oxidation of cyclohexanone with hydrogen peroxide |
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| Authors: | Rafael Llamas César Jiménez-Sanchidrián and José Rafael Ruiz |
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| Institution: | (1) Departamento de Química Orgánica, Universidad de Córdoba, Campus de Rabanales, Carretera Nacional IV-A, km. 396, 14014 Córdoba, Spain |
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| Abstract: | This paper reports the results obtained in the Baeyer-Villiger oxidation of cyclohexanone with a hydrogen peroxide/benzonitrile
mixture as oxidant in the presence of synthetic metal hydroxides or their calcined products as catalysts. The metal hydroxides
were obtained by coprecipitation. The best ε-caprolactone conversion results were provided by magnesium hydroxide. |
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| Keywords: | Baeyer-Villiger magnesium hydroxide hydrogen peroxide benzonitrile |
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