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Uniaxial extension of linear flexible-chain polymers in an extremely broad range of stresses and strain rates
Authors:G V Vinogradov  V E Dreval  E K Borisenkova  M K Kurbanaliev  V G Shalganova
Institution:(1) Institute of Petrochemical Synthesis of the USSR Academy of Science, Leninsky Prospect 29, 117912 Moscow GSP-1, USSR;(2) Tadzhik State University, Dushanbe, USSR;(3) Voronezh Branch of the All-Union Scientific, Research Institute of Synthetic Rubber, Voronezh, USSR
Abstract:Summary This work summarizes the basic patterns of strainstrength behaviour of linear flexible-chain polymers at uniaxial extension. The boundaries of transition of non-cross-linked polymers under isothermal conditions from the fluid to the high-elastic and leathery states when an axial load is applied are defined. A relationship is established between the parameters of longitudinal and low-amplitude strains. A study is made into the effect of molecular parameters and liquid media on the deformation and rupture of non-cross-linked linear polymers.With 12 figures
Keywords:High-elastic  leathery and glassy states  uniaxial extension  spurt  necking  longitudinal viscosity  modulus of high-elasticity  high-elastic recoverable strain  fracture envelope  fracture-rupture-breaking  long term durability
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