| Photopromoted Methoxycarbonylation of Olefins Under Ambient Conditions in DMF |
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| 作者姓名： | WenHaoSUN JingMeiYIN DaBinGAO GuangYunZHOU YingPingJIA XiangShengWANG |
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| 作者单位： | [1]DepartmentofChemistry＆Technology,DalianUniversityofTechnology,Dalian116012 [2]DepartmentofChemistryandChemicalEngineering,DalianUniversity,Dalian116622 |
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| 摘 要： | Photopromoted methoxycarbonylation of olefins with carbon monoxide can be carded out under ambient conditions with non-precious transition metal complexes (such as cobalt complexes) catalysts in DME The isotope experiments show that DMF is decomposed under irradiation and is conveniently used as a carbon monoxide source for the reaction.
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| 关 键 词： | 石蜡 甲酯基作用 光促进 反应条件 二甲基甲酰胺 同位素 一氧化碳 |
Photopromoted Methoxycarbonylation of Olefins Under Ambient Conditions in DMF |
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| WenHaoSUN JingMeiYIN DaBinGAO GuangYunZHOU YingPingJIA XiangShengWANG.Photopromoted Methoxycarbonylation of Olefins Under Ambient Conditions in DMF[J].Chinese Chemical Letters,2004,15(10):1245-1248. |
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| Authors: | Wen Hao SUN Jing Mei YIN Da Bin GAO Guang Yun ZHOU Ying Ping JIA Xiang Sheng WANG |
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| Institution: | Wen Hao SUN1,2,Jing Mei YIN2*,Da Bin GAO2,Guang Yun ZHOU2,Ying Ping JIA2,Xiang Sheng WANG1 1Department of Chemistry & Technology,Dalian University of Technology,Dalian 116012 2Department of Chemistry and Chemical Engineering,Dalian University,Dalian 116622 |
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| Abstract: | Photopromoted methoxycarbonylation of olefins with carbon monoxide can be carried out under ambient conditions with non-precious transition metal complexes (such as cobalt complexes) catalysts in DMF. The isotope experiments show that DMF is decomposed under irradiation and is conveniently used as a carbon monoxide source for the reaction. |
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| Keywords: | Photopromoted methoxycarbonylation carbon monoxide DMF isotope experiment |
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