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| 杯[4]芳烃黄原酸酯衍生物的合成与阳离子萃取性能 | |
| 引用本文： | 杨发福,陈希磊,郭红玉,林深,陈远荫.杯[4]芳烃黄原酸酯衍生物的合成与阳离子萃取性能[J].有机化学,2005,25(1):86-89. |
| 作者姓名： | 杨发福 陈希磊 郭红玉 林深 陈远荫 |
| 作者单位： | 1. 福建师范大学化学与材料学院,福州,350007;中国科学院福建物质结构研究所结构化学国家重点实验室,福州,350002 2. 福建师范大学化学与材料学院,福州,350007 3. 武汉大学化学系,武汉,430072 |
| 基金项目： | 国家自然科学基金，福建省自然科学基金，国家重点实验室基金 |
| 摘 要： | 以二氧六环作溶剂, 杯4]芳烃二甲氧基二羟乙氧基衍生物2与氢氧化钾、二硫化碳作用合成了杯芳烃黄原酸盐衍生物3, 并进一步与碘甲烷或氯化苄反应首次合成了含黄原酸酯基的杯芳烃衍生物4a和4b. 阳离子萃取试验表明该新型杯芳烃衍生物比单硫杂杯芳烃衍生物具有更好的过渡金属离子萃取性能. |
| 关 键 词： | 杯[4]芳烃 黄原酸酯 合成 络合 |
| 收稿时间： | 2004-2-27 |
| 修稿时间： | 2004年2月27日 |
Syntheses and Complexation Abilities of Calix[4]arene Derivatives Containing Xanthates |
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| YANG,Fa-Fu,a,b CHEN,Xi-Leia GUO,Hong-Yua LIN,Shena,b CHEN,Yuan-Yinc.Syntheses and Complexation Abilities of Calix[4]arene Derivatives Containing Xanthates[J].Chinese Journal of Organic Chemistry,2005,25(1):86-89. | |
| Authors: | YANG Fa-Fu a b CHEN Xi-Leia GUO Hong-Yua LIN Shena b CHEN Yuan-Yinc |
| Institution: | (Department of Chemistry, Fujian Normal University, Fuzhou 350007)( State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences, Fuzhou 350002)( Department of Chemistry, Wuhan University, Wuhan 430072) |
| Abstract: | Under the action of CS2 and KOH in dioxane solution, calix4]arene derivative 2 was converted into calix4]arene derivative containing xanthate salt 3. Calix4]arene derivatives containing xanthates 4a and 4b were prepared by the reaction 3 with CH3I or benzyl chloride further. The complexation abilities of novel calixarene derivatives towards transition metal ions were superior to those of monothiocalix4]arene derivatives. |
| Keywords: | calix[4]arene xanthate synthesis complexation |
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