Synthesis and Crystal Structure of 1,3-Bis(p-nitrophenoxy)propane |
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| Authors: | Muhammad Rafique Sonia Zulfiqar Glenn P. A. Yap Syed Ismat Shah Muhammad Ilyas Sarwar |
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| Affiliation: | (1) Department of Chemistry, Quaid-i-Azam University, 45320 Islamabad, Pakistan;(2) Department of Chemistry and Biochemistry, University of Delaware, Newark, DE 19716, USA;(3) Department of Physics and Astronomy, University of Delaware, Newark, DE 19716, USA;(4) Department of Materials Science and Engineering, University of Delaware, Newark, DE 19716, USA |
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| Abstract: | ![]()
Abstract The title compound 1,3-bis(p-nitrophenoxy)propane was synthesized by nucleophilic substitution of p-nitrophenol and 1,3-dibromopropane. Single crystal X-ray diffraction analysis reveals that the molecule in the solid state packs in the monoclinic P2/n space group with crystal cell parameters a = 17.465(5) ?, b = 4.8433(13) ?, c = 17.610(5) ?, β = 100.290(6)o, V = 1465.6(7) ?3, Dcalc = 1.442 g/cm−3. Two half-molecules are located in the asymmetric unit which are each completed by twofold symmetry making Z = 4, Z′ = 1. Index Abstract The title compound 1, 3-bis (p-nitrophenoxy) propane was prepared from p-nitrophenol and 1, 3-dibromopropane, crystallized from an ethanolic solution, and the structure was obtained by single crystal X-ray diffraction: monoclinic, P2/n, a = 17.465(5) ?, b = 4.8433(13) ?, c = 17.610(5) ?, β = 100.290(6)°, V = 1465.6(7) ?3.  |
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| Keywords: | Nitrophenoxypropane Crystal structure Monomer synthon |
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