| [{Pt4(en)4(NHCOtBu)4}{Tl(18-crown-6)}2](PF6)6的合成与晶体结构 |
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| 引用本文： | 吾国强,陈万芝.[{Pt4(en)4(NHCOtBu)4}{Tl(18-crown-6)}2](PF6)6的合成与晶体结构[J].无机化学学报,2006,22(4):761-764. |
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| 作者姓名： | 吾国强 陈万芝 |
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| 作者单位： | 浙江大学化学系，杭州 310028;浙江工业大学浙西分校化工系，衢州 324000,浙江大学化学系，杭州 310028 |
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| 摘 要： | The compound {Pt4(en)4(NHCOtBu)4}{Tl(18-crown-6)}2](PF6)6 has been synthesized by a simple one-pot multicomponent reaction. Its structure was determined by X-ray single crystal diffraction analysis. The cation of the compound consists of one linearly arranged Pt4(en)4(NHCOtBu)4]4+ chain and two Tl(18-crown-6)]+ ions located at the two ends of the platinum chain. The complex crystallizes in a triclinic P1 with a=1.060 5(1), b=1.252 3(1), c=2.015(2) nm, α=107.430(2)°, β=91.032(2)°, γ=101.910(2)°, V=2.489 6(4) nm3, Z=2, R1=0.074 4, wR2(I>2σ(I))=0.222 5, S=1.062. CCDC: 294083.
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| 关 键 词： | 晶体结构 铂 铊 18-冠-6 |
| 文章编号： | 1001-4861(2006)04-0761-04 |
| 收稿时间： | 2005-10-31 |
| 修稿时间： | 2006-01-12 |
Synthesis and Crystal Structure of [{Pt4(en)4(NHCOtBu)4}{Tl(18-crown-6)}2](PF6)6 |
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| WU Guo-Qiang and CHEN Wan-Zhi.Synthesis and Crystal Structure of [{Pt4(en)4(NHCOtBu)4}{Tl(18-crown-6)}2](PF6)6[J].Chinese Journal of Inorganic Chemistry,2006,22(4):761-764. |
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| Authors: | WU Guo-Qiang and CHEN Wan-Zhi |
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| Institution: | Department of Chemistry, Zhejiang University, Hangzhou 310028;Department of Chemical Engineering, West Branch of Zhejiang University of Technology, Quzhou, Zhejiang 324000 and Department of Chemistry, Zhejiang University, Hangzhou 310028 |
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| Abstract: | |
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| Keywords: | crystal structure platinum thallium 18-crown-6 |
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