| 铁邻菲咯啉、8-羟基喹啉配合物/Y型分子筛的制备、表征及催化苯酚羟化的研究 |
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| 引用本文： | 齐兴义,王国甲,叶兴凯,吴越.铁邻菲咯啉、8-羟基喹啉配合物/Y型分子筛的制备、表征及催化苯酚羟化的研究[J].化学学报,1996,54(10):988-996. |
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| 作者姓名： | 齐兴义 王国甲 叶兴凯 吴越 |
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| 作者单位： | 吉林大学化学系;中国科学院长春应用化学研究所 |
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| 摘 要： | 制备了铁邻菲咯啉、8-羟基喹啉配合物/Y型分子筛(简记为FePhen/Y,FeOx/Y)。用元素分析, TG-DTA, UV-Vis, IR, SEM, BET及XRD等方法确定了分子筛笼中金属配合物的生成及其晶体结构, 考察了实验参数对苯酚转化率及产物选择性的影响。
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| 关 键 词： | 元素分析 晶体结构 分子筛 金属络合物 羟基喹啉类 邻菲咯啉 DTA XRD SEM BET |
Studies on preparation of iron phenanthroline and 8-hydroxyquinoline complexes/Y zeolite, characterization and catalytic hydroxylation of phenol |
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| QI XINGYI,WANG GUOJIA,YE XINGKAI,WU YUE.Studies on preparation of iron phenanthroline and 8-hydroxyquinoline complexes/Y zeolite, characterization and catalytic hydroxylation of phenol[J].Acta Chimica Sinica,1996,54(10):988-996. |
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| Authors: | QI XINGYI WANG GUOJIA YE XINGKAI WU YUE |
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| Abstract: | Iron phenanthroline-and 8-hydroxyquinoline complexes/Y zeolite, denoted as FePhen/Y and FeOx/Y respectively, were prepared; The formation of the metal complexes mentioned above within the cages of Y zeolite and their crystal structures were determined by elemental analyses, diffuse reflectance UV-Vis, SEM, BET, and XRD methods. The influence of experimental parameters upon phenol conversion and product selectivities were investigated as well. |
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| Keywords: | ELEMENTAL ANALYSIS CRYSTAL STRUCTURE MOLECULAR SIEVE METAL COMPLEX HYDROXY QUINOLINES PHENANTHROLINE DTA XRD SEM BET ISOTHERM (=BRUNAUER-EMETT-TELLER ISOTHERM) |
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