An oxime-carbapalladacycle complex covalently anchored to silica as an active and reusable heterogeneous catalyst for Suzuki cross-coupling in water |
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| Authors: | Baleizão Carlos Corma Avelino García Hermenegildo Leyva Antonio |
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| Affiliation: | Instituto de Tecnología Química CSIC-UPV, Avda. de Los Naranjos s/n, 46022 Valencia, Spain. |
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| Abstract: | ![]()
A preformed oxime-carbapalladacycle complex covalently anchored onto mercaptopropyl modified silica is highly active (> 99%) for the Suzuki reaction of p-chloroacetophenone and phenylboronic acid in water; no leaching occurs and the same catalyst sample was reused eight times without decreased activity. |
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