Transient innermolecular carbene-hemicarcerand complex of fluorophenylcarbene |
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| Authors: | Lu Zhifeng Moss Robert A Warmuth Ralf Krogh-Jespersen Karsten |
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| Affiliation: | Department of Chemistry and Chemical Biology, Rutgers, The State University of New Jersey, New Brunswick, New Jersey 08903, USA. |
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| Abstract: | Laser flash photolysis of fluorophenyldiazirine incarcerated in hemicarcerand 2 affords incarcerated fluorophenylcarbene [2⊙3], which forms a metastable, innermolecular π-complex with aryl moieties of 2. This carbene complex can be observed spectroscopically. Extensive computational studies provide insights into the structure, spectroscopy, energetics, and kinetics of the 2⊙3 carbene complex. |
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