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Thermal decomposition of hydrotalcite with hexacyanoferrate(II) and hexacyanoferrate(III) anions in the interlayer |
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| Authors: | Sara J Palmer J Kristóf Veronika Vágvölgyi Erzsébet Horváth R L Frost |
| Institution: | (1) Inorganic Materials Research Program, School of Physical and Chemical Sciences, Queensland University of Technology, 2 George Street, GPO Box 2434, Brisbane, Queensland, 4001, Australia;(2) Department of Analytical Chemistry, University of Pannonia, 8201 Veszprém, PO Box 158, Pannonia, Hungary;(3) Department of Environmental Engineering and Chemical Technology, University of Pannonia, 8201 Veszprém, PO Box 158, Pannonia, Hungary |
| Abstract: | The mechanism for the decomposition of hydrotalcite remains unsolved. Controlled rate thermal analysis enables this decomposition pathway to be explored. The thermal decomposition of hydrotalcites with hexacyanoferrate(II) and hexacyanoferrate(III) in the interlayer has been studied using controlled rate thermal analysis technology. X-ray diffraction shows the hydrotalcites have a d(003) spacing of 10.9 and 11.1 Å which compares with a d-spacing of 7.9 and 7.98 Å for the hydrotalcite with carbonate or sulphate in the interlayer. Calculations show dehydration with a total loss of 7 moles of water proving the formula of hexacyanoferrate(II) intercalated hydrotalcite is Mg6Al2(OH)16Fe(CN)6]0.5·7H2O and 9.0 moles for the hexacyanoferrate(III) intercalated hydrotalcite with the formula of Mg6Al2(OH)16Fe(CN)6]0.66·9H2O. CRTA technology indicates the partial collapse of the dehydrated mineral. Dehydroxylation combined with CN unit loss occurs in two isothermal stages at 377 and 390°C for the hexacyanoferrate(III) and in a single isothermal process at 374°C for the hexacyanoferrate(III) hydrotalcite. |
| Keywords: | controlled rate thermal analysis (CRTA) hexacyanoferrate(II) hexacyanoferrate(III) hydrotalcite |
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