| The effect of the rotational excitation of NO on the stereodynamics for the reaction C(~3P)+NO(X~2Π)→CN(X~2Σ~+)+O(~3P) |
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| 引用本文： | 马建军,邹勇,刘厚通.The effect of the rotational excitation of NO on the stereodynamics for the reaction C(~3P)+NO(X~2Π)→CN(X~2Σ~+)+O(~3P)[J].中国物理 B,2013(6):338-343. |
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| 作者姓名： | 马建军 邹勇 刘厚通 |
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| 作者单位： | Department of Applied Physics, Anhui University of Technology, Maanshan 243002, China |
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| 基金项目： | Project supported by the National Natural Science Foundation of China （Grant No. 41075027）.
Many thanks to Prof. Han Ke-Li for providing the stereodynamics program. |
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| 摘 要： | The stereodynamic properties of the reaction C(3P)+NO(X2Π)→CN(X2Σ+)+O(3P) in different rotational states of reactant NO are studied theoretically by using the quasiclassical trajectory method on 2A' and 2A' potential energy surfaces(PESs) at a collision energy of 0.06 eV.The vector properties in different rotational states on the two surfaces are discussed in detail.The results indicate that the rotational excitation of NO has considerable influence on the stereodynamic property of the reaction occurring on the two surfaces.At the same time,the calculated polarization-dependent differential cross sections(PDDCSs) in different initial rotational states manifest that products are strongly polarized at three scattering angles.
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| 关 键 词： | quasiclassical trajectory vector correlation rotational excitation |
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