Synthesis and crystal structure of EnH2[IrCl6] |
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| Authors: | I. A. Baidina S. V. Korenev E. V. Makotchenko S.A. Gromilov |
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| Affiliation: | (1) Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk |
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| Abstract: | The preparation of EnH2[IrCl6] is described. Crystal data for C2H10Cl6IrN2 are: a = 6.8972(11) Å, b = 6.9435(16) Å, c = 7.3354(11) Å; α = 88.269(3)°, β = 65.495(2)°, γ = 60.305(2)°, V = 270.76(9) Å3, space group P1, Z = 1, dcalc = 2.864 g/cm3. Crystal chemical analysis of the general motif of the structure was performed by the translation sublattice identification technique. It has been found that complex anions [IrCl6]2? follow the nodes of a rather regular rhombohedral subcell with the parameters ac = 7.1 Å, αc = 64°. |
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| Keywords: | iridium powder X-ray diffraction single crystal X-ray diffraction crystal chemistry |
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