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纳米纤维状Sr3Al2O5Cl2:Eu2+,Tm3+的白色长余辉性能
引用本文:张秋函,谭慧英,刘永冲,张艺颖,汪正良.纳米纤维状Sr3Al2O5Cl2:Eu2+,Tm3+的白色长余辉性能[J].发光学报,2017,38(6):697-701.
作者姓名:张秋函  谭慧英  刘永冲  张艺颖  汪正良
作者单位:云南民族大学 化学与环境学院民族地区矿产资源综合利用重点实验室, 云南 昆明 650500
基金项目:国家自然科学基金(21261027)资助项目
摘    要:采用高温固相法在800℃下制备出系列白色长余辉荧光粉Sr3Al2O5Cl2:Eu2+,Tm3+,并研究了它们的结构、形貌及发光性能。样品Sr2.91Al2O5Cl2:0.04Eu2+,0.05 Tm3+具有单一晶相和纳米纤维结构。该样品在紫外光激发下表现出两个很强的宽带发射(分别位于~448 nm和~590 nm)。它的余辉寿命大约是20 min。利用此种荧光粉所制作出的白光LED器件表现出很强的白光发射。

关 键 词:长余辉性能  荧光粉  发光性能
收稿时间:2016-11-28

White Long Persistent Phenomenon from Sr3Al2O5Cl2:Eu2+, Tm3+ Nano-fiber
ZHANG Qiu-han,TAN Hui-ying,LIU Yong-chong,ZHANG Yi-ying,WANG Zheng-liang.White Long Persistent Phenomenon from Sr3Al2O5Cl2:Eu2+, Tm3+ Nano-fiber[J].Chinese Journal of Luminescence,2017,38(6):697-701.
Authors:ZHANG Qiu-han  TAN Hui-ying  LIU Yong-chong  ZHANG Yi-ying  WANG Zheng-liang
Institution:Key Laboratory of Comprehensive Utilization of Mineral Resource in Ethnic Regions, School of Chemistry & Environment, Yunnan Minzu University, Kunming 650500, China
Abstract:White long persistent phosphors, Sr3Al2O5Cl2∶Eu2+, Tm3+, have been successfully prepared by the solid state reaction at 800 ℃. The as-prepared sample Sr2.91Al2O5Cl2∶0.04Eu2+, 0.05 Tm3+ shares single phase and regular nano-fiber morphology. This sample exhibits two broad emission bands located at ~ 448 nm and ~ 590 nm, respectively, and its white persistent duration is about 20 min (> 0.35 mcd/m2). At last, intense white light can be found from the white light-emitting diode with Sr2.91Al2O5Cl2∶0.04Eu2+, 0.05 Tm3+.
Keywords:long persistent properties  phosphors  photo-luminescent properties
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