Acyl Iodides in Organic Synthesis. Reaction of Acyl Iodides with <Emphasis Type="Italic">N</Emphasis>,<Emphasis Type="Italic">N</Emphasis>-Dimethyl Carboxylic Acid Amides |
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| Authors: | M G Voronkov I P Tsyrendorzhieva V I Rakhlin |
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| Institution: | 1.Favorskii Irkutsk Institute of Chemistry, Siberian Division,Russian Academy of Sciences,Irkutsk,Russia |
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| Abstract: | Acyl iodides RCOI (R = Me, Ph) reacted with N,N-dimethylformamide and N,N-dimethylacetamide Me2NC(=O)R’ (R’ = H, Me) along two concurrent pathways involving transacylation and cleavage of the Me-N bond. The first pathway
leads to the formation of acyl group exchange products, and the second, to the corresponding imides R’CON(Me)COR. |
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