Structural characteristics of peroxo complexes of group IV and V transition metals. Review |
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| Authors: | V S Sergienko |
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| Institution: | (1) Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninski pr. 31, Moscow, 199991, Russia |
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| Abstract: | Structural characteristics of peroxo complexes of transition metals of Groups IV and V (Ti, V, Nb, and Ta) with the ratios M: O2 = 1: 1, 1: 2, 1: 3, and 1: 4 and alkyl peroxo complexes of Ti, Hf, and V have been considered. The structural manifestation of the trans effect of η2-coordinated peroxo ligand in pseudooctahedral Ti, Nb, and V monoperoxo complexes is characterized. The structural manifestations of the trans effect of multiply bonded peroxo and oxo ligands in monooxomonoperoxo complexes of vanadium(V) are compared. |
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