| Catalytic oxidation of cyclohexene to cyclohexanone by a triple system in acidic aqueous acetonitrile medium |
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| 作者姓名： | LI Hua-Ming YE Xing-Kai YANG Xiang-Guang WU Yue Changchun Institute of Applied Chemistry Chinese Academy of Sciences Changchun Jilin S China |
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| 作者单位： | LI，Hua-Ming YE，Xing-Kai YANG，Xiang-Guang WU，Yue Changchun Institute of Applied Chemistry，Chinese Academy of Sciences，Changchun，Jilin 13002S，China |
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| 摘 要： | The catalytic oxidation of cyclohexene to cyclohexanone using Pd(OAc)2/HQ/FePc was investigated in an acidic aqueous solution of acetonitrile. The role of each component of this system in the oxidation of cyclohexene was explored by means of UV-VIS, IR, XPS spectroscopy and cyclic voltammetry, respectively. Based on the experimental results, the mechanism of the oxidation of cyelohexene catalyzed by Pd(OAc)2/HQ/FePc was elucidated.
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Catalytic oxidation of cyclohexene to cyclohexanone by a triple system in acidic aqueous acetonitrile medium |
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| LI,Hua-Ming YE,Xing-Kai YANG,Xiang-Guang WU,Yue Changchun Institute of Applied Chemistry,Chinese Academy of Sciences,Changchun,Jilin S,China.Catalytic oxidation of cyclohexene to cyclohexanone by a triple system in acidic aqueous acetonitrile medium[J].Chinese Journal of Chemistry,1997,15(6):512-527. |
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| Authors: | LI Hua-Ming YE Xing-Kai YANG Xiang-Guang WU Yue Changchun Institute of Applied Chemistry Chinese Academy of Sciences Changchun Jilin S China |
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| Institution: | LI,Hua-Ming YE,Xing-Kai YANG,Xiang-Guang WU,Yue Changchun Institute of Applied Chemistry,Chinese Academy of Sciences,Changchun,Jilin 13002S,China |
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| Abstract: | The catalytic oxidation of cyclohexene to cyclohexanone using Pd(OAc)2/HQ/FePc was investigated in an acidic aqueous solution of acetonitrile. The role of each component of this system in the oxidation of cyclohexene was explored by means of UV-VIS, IR, XPS spectroscopy and cyclic voltammetry, respectively. Based on the experimental results, the mechanism of the oxidation of cyelohexene catalyzed by Pd(OAc)2/HQ/FePc was elucidated. |
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| Keywords: | Cyclohexene oxidation cyclohexanone hydroquinone Pd(OAc)2 iron phthalocyanine |
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