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Ketoacetal Chemistry: I. Reactions of 4,4-Diethoxy-2-trimethylsilyloxy-1-butene with Dialdehydes Acetals
Authors:O V Kharitonova  O N Pisarenko
Institution:(1) Lomonosov Moscow State Academy of Fine Chemical Processing, Moscow, 119571, Russia
Abstract:Condensation of 4,4-diethoxy-2-trimethylsilyloxy-1-butene with malonic and glutaconic aldehydes tetraethyl acetals and β-ethoxyacrolein diethyl acetal catalyzed by zinc chloride was investigated. Synthesis of 1,1,5,7-tetraethoxy-6-hepten-3-one and 1,1,5,7,7-pentaethoxy-6-nonen-3-one was performed.__________Translated from Zhurnal Organicheskoi Khimii, Vol. 41, No. 1, 2005, pp. 198–200.Original Russian Text Copyright © 2005 by Kharitonova, Pisarenko.
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