Coordination molecular hats binding acetonitrile via C-H...pi interactions |
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| Authors: | Liu Li-Xia Huang Hai-Ping Li Xin Sun Qing-Fu Sun Cui-Rong Li Yi-Zhi Yu Shu-Yan |
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| Institution: | Laboratory for Self-Assembly Chemistry, Department of Chemistry, Renmin University of China, Beijing, 100872, PR China. |
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| Abstract: | The M(3)L(3)](3+) metallo-macrocycles with syn, syn, syn conformation, self-assembled from crown ether functionalized 1,10-phenanthroline Pd(II) nitrates with naphthanoimidazole, bind a solvent CH(3)CN within the naphthanoimidazolate-built cavity through C-H...pi interactions in the crystalline state. |
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