Calix[4]quinones. Part 4: The ClO2 oxidation of calix[4]arene dialkyl ethers |
| |
Authors: | Yu-Lung Lin |
| |
Institution: | Institute of Applied Chemistry, Chinese Culture University, Taipei 11114, Taiwan, ROC |
| |
Abstract: | Except for the special case of calix4]arene diethyl ether 1, the chlorine dioxide oxidation of dialkyl ethers 2-5 yielded only the corresponding calix4]diquinone dialkyl ethers 8-11. Chlorine dioxide oxidation of calix4]arene diethyl ether 1 produced two isomeric products 6 and 7, which were stable enough to be isolated by column chromatography. However, a slow conformational interconversion between isomeric pair 6 and 7 was observed at room temperature, and the equilibrium was reached after 400 h at 18 °C with an amount of 5:3 in favor of syn-isomer. |
| |
Keywords: | Calix[4]arene Calix[4]quinone Chlorine dioxide oxidation Conformational interconversion |
本文献已被 ScienceDirect 等数据库收录! |
|