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Use of chiral sulfoxides in asymmetric synthesis

Authors:	Hélène Pellissier [Author Vitae]

Institution:	UMR n° 6180, Faculté des Sciences de Saint-Jérôme, Avenue Esc. Normandie-Niemen, 13397 Marseille Cedex 20, France

Abstract:

Keywords:	Ac acetyl Acac acetylacetone AIBN 2 2&prime -azobisisobutyronitrile Ar aryl BF₃· Et₂O boron trifluoride etherate BINAP 2 2&prime -bis(diphenylphosphanyl)-1 1&prime -binaphthyl Bn benzyl Boc tert-butoxycarbonyl Born borneol Bu butyl Cbz benzyloxycarbonyl Cod 1 5-cyclooctadiene Cy cyclohexyl dba (E E)-dibenzylideneacetone DBU 1 8-diazabicyclo[5 4 0]undec-7-ene de diastereomeric excess DIBAL diisobutylaluminium hydride DIPEA diisopropylethylamine DMAD dimethyl acetylenedicarboxylate DMF dimethylformamide Dodec dodecyl dppf 1 1&prime -bis(diphenylphosphanyl)ferrocene dr diastereomeric ratio E electrophile ee enantiomeric excess Et ethyl Hex hexyl HMDS hexamethyldisilazide isoB isoborneol LDA lithium diisopropylamide LHMDS lithium hexamethyldisilazide LICA lithium dicyclohexylamine M metal MA maleic anhydride m-CPBA 3-chloroperoxybenzoic acid Me methyl Ment menthyl Mes mesyl MOM methoxymethyl Naph naphthyl NMM N-methylmaleimide NMO N-methylmorpholine N-oxide NPM N-phenylmaleimide Pent pentyl Ph phenyl Piv pivaloyl PMB p-methoxybenzoyl PMP p-methoxyphenyl Pr propyl PTAD phenyltriazolinedione Py pyridine TBAF tetra-n-butylammonium fluoride TBDMS tert-butyldimethylsilyl Tf trifluoromethanesulphonyl TFAA trifluoroacetic anhydride THF tetrahydrofuran THP tetrahydropyranyl TIP triisopropylphenyl TIPS triisopropylsilyl TMS trimethylsilyl TMSOTf trimethylsilyl trifluoromethanesulphonate Tol tolyl Ts 4-toluenesulphonyl (tosyl)
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