Kinetics of supramolecular crystallization of concentrated suspensions of monodisperse spherical silica particles |
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| Authors: | V. V. Serdobintseva A. F. Danilyuk S. V. Vosel D. V. Kalinin |
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| Affiliation: | (1) Institute of Mineralogy and Petrography, 630090 Novosibirsk, Russia;(2) Boreskov Institute of Catalysis, 630090 Novosibirsk, Russia |
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| Abstract: | The kinetics of supramolecular crystallization of concentrated suspensions is three-dimensional and follows the Avrami-Erofeev equation: A=1-exp[-(kt)m], where m=4. The rate constant k is proportional to the probability of the appearance of a crystallization center in unit volume in unit time and the linear crystal growth rate, which is determined experimentally. |
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| Keywords: | Silica monodisperse particles supramolecular crystallization kinetics |
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