A new thermo‐responsive block copolymer with tunable upper critical solution temperature and lower critical solution temperature in the alcohol/water mixture |
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| Authors: | Yang Su Meihan Dan Xin Xiao Xiaohui Wang Wangqing Zhang |
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| Institution: | Key Laboratory of Functional Polymer Materials of the Ministry of Education, Institute of Polymer Chemistry, Nankai University, , Tianjin, 300071 China |
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| Abstract: | The multi‐thermo‐responsive block copolymer of poly2‐(2‐methoxyethoxy)ethyl methacrylate]‐block‐polyN‐(4‐vinylbenzyl)‐N,N‐diethylamine] (PMEO2MA‐b‐PVEA) displaying phase transition at both the lower critical solution temperature (LCST) and the upper critical solution temperature (UCST) in the alcohol/water mixture is synthesized by reversible addition‐fragmentation chain transfer polymerization. The poly2‐(2‐methoxyethoxy)ethyl methacrylate] (PMEO2MA) block exhibits the UCST phase transition in alcohol and the LCST phase transition in water, while the polyN‐(4‐vinylbenzyl)‐N,N‐diethylamine] (PVEA) block shows the UCST phase transition in isopropanol and the LCST phase transition in the alcohol/water mixture. Both the polymer molecular weight and the co‐solvent/nonsolvent exert great influence on the LCST or UCST of the block copolymer. By adjusting the solvent character including the water content and the temperature, the block copolymer undergoes multiphase transition at LCST or UCST, and various block copolymer morphologies including inverted micelles, core‐corona micelles, and corona‐collapsed micelles are prepared. © 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2013, 51, 4399–4412 |
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| Keywords: | block copolymers lower critical solution temperature (LCST) micelles poly[N‐(4‐vinylbenzyl)‐N N‐diethylamine] stimuli‐sensitive polymers upper critical solution temperature (UCST) |
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