Kinetics and mechanism of oxidation of malonic acid by permanganate and manganese dioxide in acid perchlorate medium |
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| Authors: | Indu Rao Som K Mishra Prem D Sharma |
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| Institution: | (1) Department of Chemistry, University of Rajasthan, 302 004 Jaipur, India |
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| Abstract: | Summary The kinetics of oxidation of malonic acid by both MnO4]– and MnO2 have been studied in an HClO4 medium. The oxidation product of the organic acid was found to be glyoxylic acid. A reaction mechanism assuming complexation between MnO2 and malonic acid is suggested. The rate is independent of H+]. |
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