| 氮杂冠醚聚硅氧烷固定液的色谱保留机理 |
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| 引用本文： | 上官云凤,臧旭.氮杂冠醚聚硅氧烷固定液的色谱保留机理[J].分析科学学报,1996,12(2):98-102. |
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| 作者姓名： | 上官云凤 臧旭 |
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| 作者单位： | 武汉大学化学系 |
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| 摘 要： | 氨杂冠醚聚硅氧烷是一类呈中等极性的新颖气相色谱固定液．本文通过测定醇、酯、卤代烃和苯系列化合物的色谱保留值和相应势力学参数，研究它对上述不同化合物的保留机理及其分子识别的热力学性质
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| 关 键 词： | 冠醚 固定液 毛细管 气相色谱 色谱保留机理 |
Chromatographic Retention Mechanisms of Aza-Crown Ether Polysiloxane Stationary Phases |
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| Shangguan Yunfeng,Zang Xu,qiu Wenli,Wu Caiying.Chromatographic Retention Mechanisms of Aza-Crown Ether Polysiloxane Stationary Phases[J].Journal of Analytical Science,1996,12(2):98-102. |
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| Authors: | Shangguan Yunfeng Zang Xu qiu Wenli Wu Caiying |
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| Abstract: | Aza-crown ether polysloxane(PUAC-15-C-5 or PUAC-18-C6) is a new medium-po-rarity stationary phase that exhibits excellent selectivity for non-polar compounds ,easily polariz-able aromatic compounds and polar compounds.Their separation mechanisms and thermodynamic characterization of molecular recognzation have been investigated by measuring various chromatographic retention data and thermodynamic parameters of alcohols,esters,aromatic compounds,substituted phenol and halohydrocarbon.The selective separation of bentonal isomers on PUAC-15-C-5 column is made as example. |
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| Keywords: | Crown ether staionary liquid Capillary gas chromatography Chromatographic retention mechanism |
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