| 硝基芴桐类化合物与芳香胺相互作用的电子吸收光谱研究 |
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| 引用本文： | 李. 硝基芴桐类化合物与芳香胺相互作用的电子吸收光谱研究[J]. 化学学报, 1989, 47(4): 393-395 |
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| 作者姓名： | 李 |
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| 作者单位： | 复旦大学材料科学系 |
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| 基金项目： | 国家自然科学基金，复旦科学基金 |
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| 摘 要： | 本文研究不同结构的芳香胺和硝基芴酮形成的基态电荷转移复合物, 讨论结构和溶剂对基吸收光谱的影响.
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| 关 键 词： | 铵化合物 硝基化合物 吸收光谱法 芴酮P 芳香族化合物 电荷转移络合物 电荷转移态 相互作用 |
A study on absorption spectra of charge-transfer complexes between nitro-substituted fluorenones and aromatic amines |
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| LI. A study on absorption spectra of charge-transfer complexes between nitro-substituted fluorenones and aromatic amines[J]. Acta Chimica Sinica, 1989, 47(4): 393-395 |
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| Authors: | LI |
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| Abstract: | The electronic spectra of the charge-transfer complexes (CTC) between aromatic amines as donors and nitrofluorenones as acceptors were studied. The CTC peak showed a red shift, and the equilibrium constant increased with increasing electron-donating or electron-accepting ability of the components. In polar solvents the absorption peak moved to shorter wavelengths, and in electron-donating solvents the equilibrium constant was decreased. |
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| Keywords: | AMMONIUM COMPOUND NITRO COMPOUNDS ABSORPTION SPECTROMETRY FLUORENONE P AROMATIC COMPOUNDS CHARGE TRANSFER COMPLEX CHARGE TRANSFER STATES INTERACTIONS |
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