Chirality control in oligothiophene through chiral wrapping |
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| Authors: | Sanji Takanobu Kato Nobu Tanaka Masato |
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| Institution: | Chemical Resources Laboratory, Tokyo Institute of Technology, Midori-ku, Yokohama, Japan. sanji@res.titech.ac.jp |
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| Abstract: | structure: see text] Mixing oligothiophenes and polysaccharides, such as amylose and schizophyllan, affords novel inclusion complexes, in which oligothiophene guests adopt twisted conformation in the chiral channel created by left- or right-handed helical wrapping with the polysaccharide host polymers, leading to optical activity. |
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