| Synthesis and crystal structure of a novel two-dimensional network complex [Mn(O_2CCH_2Cl)_2(phen)]_n |
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| 作者姓名： | LI Jun ZHANG Jinhua WU Aizhi XI Yun GUO Hui & ZHANG Fengxing |
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| 作者单位： | LI Jun，ZHANG Jinhua，WU Aizhi，XI Yun，GUO Hui & ZHANG Fengxing Department of Chemistry，Northwest University/Shaanxi Province Key Laboratory of Physicoinorganic Chemistry，Xi'an 710069，China |
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| 基金项目： | the National Natural Science Foundation of China，陕西省自然科学基金 |
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| 摘 要： | A novel two-dimensional network manganese(Ⅱ) polymer complex Mn(O2CCH2CI)2-(phen)]n has been synthesized and characterized by elemental analysis and IR spectrum. The crystal structure of title complex has also been determined, which is in monoclinic of a space group P21/c with the following unit cell parameters at 294K: a =1.9738(4) nm, b =1.1384(2) nm, c =0.74915(14) nm, V=1.6795(5) nm3, Z= 2.
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Synthesis and crystal structure of a novel two-dimensional network complex [Mn(O2CCH2Cl)2(phen)]n |
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| LI Jun,ZHANG Jinhua,WU Aizhi,XI Yun,GUO Hui & ZHANG Fengxing.Synthesis and crystal structure of a novel two-dimensional network complex [Mn(O_2CCH_2Cl)_2(phen)]_n[J].Science in China(Chemistry),2005,48(Z1). |
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| Authors: | LI Jun ZHANG Jinhua WU Aizhi XI Yun GUO Hui ZHANG Fengxing |
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| Institution: | Department of Chemistry, Northwest University/Shaanxi Province Key Laboratory of Physicoinorganic Chemistry, Xi'an 710069, China |
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| Abstract: | A novel two-dimensional network manganese(Ⅱ) polymer complex Mn(O2CCH2CI)2-(phen)]n has been synthesized and characterized by elemental analysis and IR spectrum. The crystal structure of title complex has also been determined, which is in monoclinic of a space group P21/c with the following unit cell parameters at 294K: a=1.9738(4) nm, b =1.1384(2) nm, c =0.74915(14) nm, V =1.6795(5) nm3, Z= 2. |
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| Keywords: | synthesis polymer manganese complex two-dimensional network |
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