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| STRUCTURE CHARACTERIZATION AND CATALYTICACTIVITY TEST OF Ni(II) COMPLEXES CONTAINING2-(DIPHENYLPHOSPHINOAMINO) PYRIDINE(PAP) | |
| 引用本文： | HUANG Wei-Ping, ZHANG Xin-Jie, WU Shi-HuaMA Shu-Yin, ZHANG Shu-Ji, ZHAO Wei-Jun(Deparfment of Chemistry,Nankai University Tianjin 300071)(This project is supported by the National Natural Science Foundation of China and State Key Laboratory of C1 Chemic. STRUCTURE CHARACTERIZATION AND CATALYTICACTIVITY TEST OF Ni(II) COMPLEXES CONTAINING2-(DIPHENYLPHOSPHINOAMINO) PYRIDINE(PAP)[J]. 天然气化学杂志, 1997, 6(3): 252-257 |
| 作者姓名： | HUANG Wei-Ping ZHANG Xin-Jie WU Shi-HuaMA Shu-Yin ZHANG Shu-Ji ZHAO Wei-Jun(Deparfment of Chemistry Nankai University Tianjin 300071)(This project is supported by the National Natural Science Foundation of China and State Key Laboratory of C1 Chemic |
| 作者单位： | HUANG Wei-Ping; ZHANG Xin-Jie; WU Shi-HuaMA Shu-Yin; ZHANG Shu-Ji; ZHAO Wei-Jun(Deparfment of Chemistry，Nankai University Tianjin 300071 |
| 摘 要： | IntroductionIn1962,N.V.Kutepow'SgroupfirstusedcomplexesofFe,CoandNiascatalyststocatalyzecarboXylationofethanoltopreparepropanoicacidanditsderivants.Thereactionpressurewashighandtheyieldwaslow.LateronPaulalsandhiscolleagueusedabC13andiodineascatalyst,which… |
STRUCTURE CHARACTERIZATION AND CATALYTIC ACTIVITY TEST OF Ni(II) COMPLEXES CONTAINING 2-(DIPHENYLPHOSPHINOAMINO) PYRIDINE(PAP) |
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| Weiping Huang,Xinjie Zhang,Shihua Wu,Shuyin Ma,Shuji Zhang,Weijun Zhao. STRUCTURE CHARACTERIZATION AND CATALYTIC ACTIVITY TEST OF Ni(II) COMPLEXES CONTAINING 2-(DIPHENYLPHOSPHINOAMINO) PYRIDINE(PAP)[J]. Journal of Natural Gas Chemistry, 1997, 6(3): 252-257 | |
| Authors: | Weiping Huang Xinjie Zhang Shihua Wu Shuyin Ma Shuji Zhang Weijun Zhao |
| Affiliation: | Naikai University |
| Abstract: | TWo complexes Ni(PAP)Cl2, Ni(PAP)2Cl2 were synthesized and characterized with IR. The IR data show that Ni(II) in Ni(PAP)2Cl2 is octahedral Structure and the electron donor atoms 2Cl, ZP and 2N are in trans position. The molecular structure of Ni(PAP)Cl2 shows that center nickel atom has square-planar configuration. All donor atoms. nickel atom and pyridine cycle are located almost in the same plane. Both the two complexes are of good catalytic activity for carboxylation of ethanol. |
| Keywords: | :nickel complex 2 -(diphenylphosphinoamino)pyridine carboxylation ethanol |
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