Thioether containing ligands for asymmetric allylic substitution reactions |
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| Affiliation: | 1. Departamento de Química Inorgánica, Facultad de Química, Universidad Nacional Autónoma de México, Cd. Universitaria, 04510 Mexico DF, Mexico;2. Departament de Química Física i Inorgànica, Universitat Rovira i Virgili, C/Marcel.lí Domingo s/n, Tarragona, Spain |
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| Abstract: | This review covers reports in the literature on the use of thioether ligands in Pd-catalysed asymmetric allylic substitution reactions from 1996 to June 2006. In the first section, we will cover the results using (S,S)-homo and (S,S)-heterodonor ligands. In the next section, we will present the results using heterodonor (S,X)-ligands, emphasizing the results obtained with (S,N)- and (S,P)-donor ligands. We also discuss any reported mechanistic aspects according to the allylic substitution results. |
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