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贵州瓮福地区磷尾矿中钙、镁、磷的赋存状态测定
引用本文:金绍祥,杨涛.贵州瓮福地区磷尾矿中钙、镁、磷的赋存状态测定[J].理化检验(化学分册),2012(5):590-593.
作者姓名:金绍祥  杨涛
作者单位:贵州有色地质化验监测中心;贵州省有色金属和核工业地质勘查局物化探总队
摘    要:应用化学组分分析、X射线衍射分析、扫描电子显微镜及X射线能谱法等多种方法对贵州省瓮福地区磷尾矿中钙、镁及磷的赋存状态作了分析和研究。结果表明:①选自该矿区的磷尾矿为高镁(wMgO17.26%~17.65%),高钙(wCaO34.11%~34.56%),低磷(wP2O55.30%~5.69%)的固体矿物;②尾矿中镁主要以白云石形式存在,并有少量以磷酸盐和硅酸盐形式存在;钙主要也以白云石形式存在,加上少量以方解石和磷酸盐形式存在;磷主要以磷灰石形式存在,有少量存在于铁氧化物及独居石、磷钇矿中。

关 键 词:赋存状态  磷尾矿      

Determination of Naturally Endowed States of Calcium,Magnesium and Phosphorus in Phosphorite Tailings Sampled from Wengfu District of Guizhou Province
JIN Shao-xiang,YANG Tao.Determination of Naturally Endowed States of Calcium,Magnesium and Phosphorus in Phosphorite Tailings Sampled from Wengfu District of Guizhou Province[J].Physical Testing and Chemical Analysis Part B:Chemical Analgsis,2012(5):590-593.
Authors:JIN Shao-xiang  YANG Tao
Institution:1.Guizhou Analytical and Monitoring Center of Non-ferrous Metals,Duyun 558004,China; 2.General Team of Physical and Chemical Prospection,Guizhou Provincial Geological Prospection Bureau of Non-ferrous Metals and Nuclear Industry,Duyun 558004,China)
Abstract:Naturally endowed states of calcium,magnesium and phosphorus in phosphorite tailings sampled from Wengfu district of Guizhou province were studied and analyzed by chemical analysis,X-ray diffraction analysis,scanning electron microscopy and X-ray photoelectron spectrometry.It was found that: ① the phosphorite tailings sampled from the ore slag were solid minerals containing high magnesium(wMgO 17.26%-17.65%),high calcium(wCaO 34.11%-34.56%) and low phosphorus(wP2O5 5.30%-5.69%).② Magnesium in the tailings was mainly present in form of dolomite with small amounts present as phosphate and silicate;calcium was also present mainly as dolomite with small amounts present as calcite and phosphate;phosphorus was present mainly as apatite with small amounts occurred in iron oxide,monazite and xenotime.
Keywords:Naturally endowed states  Phosphorite tailings  Calcium  Magnesium  Phosphorus
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