| 基于柔性1，4-苯二硫乙酸配体构筑的二维锰配合物的合成、晶体结构及磁性 |
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| 引用本文： | 王晓娟,尹建玲,陈 静,冯云龙.基于柔性1，4-苯二硫乙酸配体构筑的二维锰配合物的合成、晶体结构及磁性[J].无机化学学报,2011,27(2):367-371. |
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| 作者姓名： | 王晓娟 尹建玲 陈 静 冯云龙 |
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| 作者单位： | 浙江师范大学物理化学研究所,浙江省固体表面反应化学重点实验室,金华,321004 |
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| 摘 要： | 水热法合成了一个基于1,4-苯二硫乙酸(H2L)柔性配体的Mn(Ⅱ)配合物Mn3L3(phen)2]n,并通过元素分析,红外光谱、热失重和X-射线单晶衍射实验对其结构进行了表征。结构分析表明,配合物是一个包含三核锰结构单元的二维层面结构。对配合物的变温磁化率研究表明,在三核锰离子间存在弱的反铁磁交换作用。
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| 关 键 词： | Mn(Ⅱ)配合物 水热合成 1 4-苯二硫乙酸 晶体结构 磁性 |
A New 2D Layer Manganese(11) Complex Assembled by Flexible 1,4-Benzenebis(thioacetic acid) Ligand:Synthesis,Crystal Structure and Magnetic Property |
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| WANG Xiao-Juan,YIN Jian-Ling,CHEN Jing and FENG Yun-Long.A New 2D Layer Manganese(11) Complex Assembled by Flexible 1,4-Benzenebis(thioacetic acid) Ligand:Synthesis,Crystal Structure and Magnetic Property[J].Chinese Journal of Inorganic Chemistry,2011,27(2):367-371. |
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| Authors: | WANG Xiao-Juan YIN Jian-Ling CHEN Jing and FENG Yun-Long |
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| Institution: | Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua, Zhejiang 321004, China,Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua, Zhejiang 321004, China,Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua, Zhejiang 321004, China and Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua, Zhejiang 321004, China |
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| Abstract: | A new Mn(II) complex based on 1,4-benzenebis(thioacetic acid) (HZL), Mn3L3(phen)Z]n (1, phen=1,10-phenanthroline), has been hydrothermally synthesized and characterized by single, crystal X-ray diffraction,elemental analysis, IR spectrum, and TG analysis. The structure can be considered as a two-dimensional (2D)layered architecture which consists of linear trinuclear Mn (II) units. The magnetic susceptibility data are interpreted with the linear trinuclear law, yielding J and g values of-1.95(5) cm(-1) and 1.98(1). The exchange integral (J) indicates a weak antiferromagnetie interactions in the linear trinuclear Mn(II) unit. CCDC: 734943. |
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| Keywords: | Mn(Ⅱ) complex hydrothermal synthesis 1 4-benzenebis(thioacetic acid) crystal structure magnetic property |
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