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Thermodiffusion and Morphological Stability in Convectionless Crystal Growth Systems from Melts and Melt-Solutions
Authors:P. Rudolph  T. Boeck  P. Schmidt
Abstract:Crystal growth experiments of multicomponent systems under microgravity require an exact analysis of the diffusion phenomena in the nutrient fluid phase. The contribution of the Soret effect to the transport and distribution of matter in a convectionless casting arrangement for shaped crystal growth and in THM melt-solution zones have been investigated. Some semiconductor systems were analysed from experimental (Bi1-xSbx mixed crystals) and theoretical (PbTe, InP, GaAs, CdTe compounds) point of view. The criterion for constitutional supercooling was correspondingly modified. It has been distinguished between associated (AIV BVI, AII BVI) and dissociated (AIII–BV) melt-solutions, containing different species of diffusion (molecules or atoms, respectively).
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