Enantioselective catalysis of hetero Diels-Alder reaction and diethylzinc addition using a single catalyst |
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| Authors: | Du Haifeng Ding Kuiling |
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| Institution: | State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Road, Shanghai 200032, The People's Republic of China. |
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| Abstract: | reaction: see text] Integration of two asymmetric reactions in one pot with the promotion of a single catalyst has been achieved in high efficiency and excellent stereoselectivity for hetero Diels-Alder reaction of Danishefsky's diene and diethylzinc addition to aldehydes. The strategy described in the present work demonstrated the ability of a single catalyst to promote two distinct enantioselective reactions in one pot. |
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