| 含能材料热动力学行为和热力学性质的研究进展 |
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| 引用本文： | 赵凤起,曲文刚,高红旭,罗阳.含能材料热动力学行为和热力学性质的研究进展[J].中国科学:化学,2014(6):953-963. |
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| 作者姓名： | 赵凤起 曲文刚 高红旭 罗阳 |
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| 作者单位： | 西安近代化学研究所燃烧与爆炸技术重点实验室,西安710065 |
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| 基金项目： | 国家自然科学基金（21173163）资助 |
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| 摘 要： | 针对近年来含能材料热力学和热动力学分析研究方面所取得的一些进展进行了回顾和概述;对新型含能材料如含能离子盐、FOX-7及其衍生物、新型高能氧化剂及高能添加剂等的热动力学行为和热力学性质进行了系统总结.此外,介绍了目前最新的一些研究方法和理论,讨论了当前研究中存在的问题,同时对未来的发展方向进行了展望.
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| 关 键 词： | 含能材料 热动力学行为 热力学性质 |
Recent advances in the study of thermodynamic properties and thermokinetic behavior of energetic materials |
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| ZHAO FengQi,QU WenGang,GAO HongXu,LUO Yang.Recent advances in the study of thermodynamic properties and thermokinetic behavior of energetic materials[J].Scientia Sinica Chimica,2014(6):953-963. |
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| Authors: | ZHAO FengQi QU WenGang GAO HongXu LUO Yang |
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| Institution: | (Science and Technology on Combustion and Explosion Laboratory, Xi＇an Modern Chemistry Research Institute Xi＇an 710065, China) |
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| Abstract: | This review gives an overview of the recent advances in the thermodynamic properties and thermokinetic behavior of energetic materials （EMs）. The kinetic behavior of decomposition reaction, thermochemical properties of the dissolution process and the specific heat capacity of novel energetic materials including the energetic triazole ionic salts, FOX-7 and its derivatives, high energetic additives and high energetic oxidizers are systematically summarized, and some novel research methods and theories are introduced. In addition, perspectives of the development and the puzzles in the current are also discussed. |
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| Keywords: | energetic materials thermokinetic behavior thermodynamic properties |
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