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| 一些含氟单体的合成及其聚合反应的初步研究 | |
| 引用本文： | 唐婷,杨雪艳,吴范宏.一些含氟单体的合成及其聚合反应的初步研究[J].化学学报,2010,68(8):803-808. |
| 作者姓名： | 唐婷 杨雪艳 吴范宏 |
| 作者单位： | 1. 杭州师范大学医药卫生管理学院药学教研室,杭州,310036 2. 华东理工大学化学与分子工程学院,上海,200237 3. 华东理工大学化学与分子工程学院,上海,200237;中国科学院上海有机化学研究所,有机氟化学重点实验室,上海,200237 |
| 摘 要： | 合成了含氟单体3-氧杂全氟戊烷-1,5-二磺酰溴(3),N-烯丙基-2-(ω-碘-n-全氟烷氧基)-1,1,2,2-四氟乙磺酰胺(16～18).初步研究了含氟单体3与非共轭二烯的聚合反应、连二亚硫酸钠引发的含氟单体16～18的聚合反应以及α,ω-全氟烷基二碘代烷22,23与非共轭端二烯的聚合反应,得到了相应的含氟聚合物或寡聚物. |
| 关 键 词： | 含氟聚合物 连二亚硫酸钠 聚合 |
| 收稿时间： | 2009-06-23 |
| 修稿时间： | 2009-10-27 |
Synthesis of Several Fluorine-containing Monomers and Their Polymerization Reaction |
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| Tang Ting,Yang Xueyan,Wu Fanhong.Synthesis of Several Fluorine-containing Monomers and Their Polymerization Reaction[J].Acta Chimica Sinica,2010,68(8):803-808. | |
| Authors: | Tang Ting Yang Xueyan Wu Fanhong |
| Institution: | ( Pharmaceutical Sciences Department, Medicine and Health Manage College, Hangzhou Normal University, Hangzhou 310036) (School of Chemistry and Molecular Engineering, East China University of Science and Technology, Shanghai 200237) ( Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032) |
| Abstract: | Synthesis of fluorine-containing monomers 3-oxa-perfluoropentane-1,5-disulfonyl bromide (3), N-allyl-2-(ω-iodo-n-perfluoroalkyloxy)-1,1,2,2-tetrafluoroethylsulfonamides (16～18) was realized. The copolymerization reaction of 3 with nonconjugated dienes, the polymerization of 16～18 and the copoly- merization of α,ω-perfluoroalkylenediiodides 22, 23 with nonconjugated dienes initiated by sodium dithio- nite were performed to give corresponding fluorine-containing polymers. |
| Keywords: | fluorine-containing polymer sodium dithionite polymerization |
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